G. Schroeder et al., Studies of reaction heats and structures of complexes formed between macrocompounds and SbCl5 in CCl4, J MOL STRUC, 526, 2000, pp. 159-163
The heats of reactions between the acyclic and cyclic macro-compounds are d
etermined. The values can be used as a measure of the donor abilities of th
e macro ligands. Formation of two types of complexes between the macro comp
ounds and SbCl5 is established. The acyclic macro-compounds form 1:1 comple
xes, whereas the macrocyclic compounds only 1:2 complexes. (C) 2000 Elsevie
r Science B.V. All rights reserved.