Studies of reaction heats and structures of complexes formed between macrocompounds and SbCl5 in CCl4

Citation
G. Schroeder et al., Studies of reaction heats and structures of complexes formed between macrocompounds and SbCl5 in CCl4, J MOL STRUC, 526, 2000, pp. 159-163
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
526
Year of publication
2000
Pages
159 - 163
Database
ISI
SICI code
0022-2860(20000810)526:<159:SORHAS>2.0.ZU;2-Y
Abstract
The heats of reactions between the acyclic and cyclic macro-compounds are d etermined. The values can be used as a measure of the donor abilities of th e macro ligands. Formation of two types of complexes between the macro comp ounds and SbCl5 is established. The acyclic macro-compounds form 1:1 comple xes, whereas the macrocyclic compounds only 1:2 complexes. (C) 2000 Elsevie r Science B.V. All rights reserved.