Unprecedented effects of the trimethylsilyl group on the reactivity of 3C-silylated silacyclopentenes and their derivatives

Authors
Boukherroub, R Manuel, G
Citation
R. Boukherroub et G. Manuel, Unprecedented effects of the trimethylsilyl group on the reactivity of 3C-silylated silacyclopentenes and their derivatives, J ORGMET CH, 604(2), 2000, pp. 141-149
Citations number
34
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
604
Issue
2
Year of publication
2000
Pages
141 - 149
Database
ISI
SICI code
0022-328X(20000616)604:2<141:UEOTTG>2.0.ZU;2-6
Abstract
We have synthesised new 3C-silylated silacyclopentenes from the correspondi ng 3-trimethylsilyl-1,1-dichloro-1-silacyclopent-3-enes. The presence of tw o metal centres M (M = Si) in alpha and beta-positions confers an original structure for these new heterocycles. The chemical behaviour of such compou nds and their derivatives was studied and compared to the results obtained in the non-substituted silacyclopentane series. (C) 2000 Elsevier Science S .A. All rights reserved.