First structural characterization of completely alkyl-substituted Al-Sb Lewis acid-base adducts

Authors
Schulz, S Kuczkowski, A Nieger, M
Citation
S. Schulz et al., First structural characterization of completely alkyl-substituted Al-Sb Lewis acid-base adducts, J ORGMET CH, 604(2), 2000, pp. 202-207
Citations number
39
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
604
Issue
2
Year of publication
2000
Pages
202 - 207
Database
ISI
SICI code
0022-328X(20000616)604:2<202:FSCOCA>2.0.ZU;2-E
Abstract
Several Lewis acid-base adducts R3Al <-- SbR3' (R' = Et, R = Me (1), Et (2) , t-Bu C3); R' = n-Pr, R = Me (4), Et (5), t-Bu (6); R' = i-Pr, R = Me (7), Et (8), t-Bu (9); R' = sec-Bu, R = Me (10), Pt (11), r-Bu (12); R' = t-Bu, R = Me (13), Et (14), t-Bu (15) were obtained by reaction of aluminum tria lkyls R,AI and the corresponding antimony trialkyls R;Sb. For the first tim e, solid state structures of all-alkyl substituted AI-Sb adducts (3, 9. 13, 14) were determined by single crystal X-ray analysis. (C) 2000 Elsevier Sc ience S.A. All rights reserved.