The conventional method of the determination of enthalpy change at ion solvation in solutions: Is it correct?

Authors
Zolotoy, NB Karpov, GV
Citation
Nb. Zolotoy et Gv. Karpov, The conventional method of the determination of enthalpy change at ion solvation in solutions: Is it correct?, J PHYS CH B, 104(31), 2000, pp. 7468-7470
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHYSICAL CHEMISTRY B
ISSN journal
15206106 → ACNP
Volume
104
Issue
31
Year of publication
2000
Pages
7468 - 7470
Database
ISI
SICI code
1520-6106(20000810)104:31<7468:TCMOTD>2.0.ZU;2-8
Abstract
It is shown that the conventional (using the Born-Haber cycle) method of th e determination of enthalpy change at ion solvation in solutions gives inco rrect values for this fundamental parameter. A new experimental method free from the defects of the conventional one is presented.