Flux synthesis and isostructural relationship of cubic Na1.5Pb0.75PSe4, Na0.5Pb1.75CeS4, and Li0.5Pb1.75GeS4

Na1.5Pb0.75PSe4 was synthesized by the reaction of Pb with a molten mixture of Na2Se/P2Se5/Se at 495 degrees C, Na0.5Pb1.75GeS4 was synthesized by rea cting Pb and Ge in molten Na2Sx at 530 degrees C. Likewise, Li0.5Pb1.75GeS4 can be synthesized in a Li2Sx flux at 500 degrees C. Na0.5Pb1.75GeS4 and L i0.5Pb1.75GeS4 are relatively air- and water-stable, while Na1.5Pb0.75PSe4 is only stable in air and water for less than 1 day. The structures of all three compounds were determined by single-crystal X-ray diffraction. The co mpounds crystallize in the cubic, noncentrosymmetric space group I (4) over bar 3d with a = 14.3479(2) Angstrom, Z = 16, R1 = 0.0226, and wR2 = 0.0517 for Na1.5Pb0.75PSe4, a = 14.115(1) Angstrom, Z = 16, R1 = 0.0284, and wR2 = 0.0644 for Na0.5Pb1.75GeS4, and a = 14.0163(6) Angstrom, Z = 16, R1 = 0.0 273, and wR2 = 0.0637 for Li0.5Pb1.75GeS4. The compounds adopt a structure that is similar to that of Ba3CdSn2S8 and feature [PSe4](3-) or [GeS4](4-) tetrahedral building blocks. In this three-dimensional structure, there are two types of metal sites. In each structure, these sites are occupied diff erently because of a disorder between the alkali and lead cations, All thre e compounds are semiconductors with band gaps around 2 eV, The observation of a large second harmonic generation (SHG) signal for Na0.5Pb1.75GeS4 indi cates that it may be a potential nonlinear optical (NLO) material. Infrared and Raman spectroscopic characterization is also reported. (C) 2000 Academ ic Press.