SYNTHESIS AND CHARGE-DEPENDENT BINDING-AFFINITY OF A NEW REDOX-ACTIVEPOLYMERIC LIGAND

Authors
ALLGEIER AM MIRKIN CA
Citation
Am. Allgeier et Ca. Mirkin, SYNTHESIS AND CHARGE-DEPENDENT BINDING-AFFINITY OF A NEW REDOX-ACTIVEPOLYMERIC LIGAND, Organometallics, 16(13), 1997, pp. 3071-3073
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
13
Year of publication
1997
Pages
3071 - 3073
Database
ISI
SICI code
0276-7333(1997)16:13<3071:SACBOA>2.0.ZU;2-R
Abstract
The synthesis and characterization of a new, polymeric, redox-active l igand with switchable binding affinities for transition metals are rep orted. Polymer 2 is based on p-ferrocenylphenyl acrylate and complexes the (eta(5)-C5Me5)Ru+ fragment. Oxidation of the polymeric ligand cha nges its binding constant for Ru by over two orders of magnitude.