SYNTHESIS AND CHARACTERIZATION OF (MESGAO)(9) (MES=ME3C6H2) AND CRYSTAL-STRUCTURE OF THE FIRST GALLOXANE COMPARABLE TO CATALYTICALLY ACTIVEALUMINUM COMPOUNDS

Authors
STORRE J KLEMP A ROESKY HW FLEISCHER R STALKE D
Citation
J. Storre et al., SYNTHESIS AND CHARACTERIZATION OF (MESGAO)(9) (MES=ME3C6H2) AND CRYSTAL-STRUCTURE OF THE FIRST GALLOXANE COMPARABLE TO CATALYTICALLY ACTIVEALUMINUM COMPOUNDS, Organometallics, 16(13), 1997, pp. 3074-3076
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
13
Year of publication
1997
Pages
3074 - 3076
Database
ISI
SICI code
0276-7333(1997)16:13<3074:SACO((>2.0.ZU;2-6
Abstract
The thermolysis of (Mes(2)GaOH)(2) . THF in toluene or 1,4-dioxane at 100 degrees C resulted in the formation of (MesGaO)(9) (1). A byproduc t of this reaction is Mes(3)Ga. Compound 1 was characterized by electr on impact mass spectroscopy and single-crystal X-ray structural analys is. The structure consists of two six-membered (MesGaO)(3) rings conne cted by three mu(2)-(MesGaO) units.