Rheological behavior of concentrated bitumen in water emulsions

Citation
Ga. Nunez et al., Rheological behavior of concentrated bitumen in water emulsions, LANGMUIR, 16(16), 2000, pp. 6497-6502
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LANGMUIR
ISSN journal
07437463 → ACNP
Volume
16
Issue
16
Year of publication
2000
Pages
6497 - 6502
Database
ISI
SICI code
0743-7463(20000808)16:16<6497:RBOCBI>2.0.ZU;2-Y
Abstract
The effect of bitumen concentration and mean drop diameter and distribution on the rheological behavior of bitumen in water emulsions was investigated . Results obtained showed that the emulsion viscosity is severely affected by the type of drop size distribution. In fact, emulsions with a bimodal dr op diameter distribution exhibit viscosity values which were at least 1 ord er of magnitude lower than the viscosity of similar emulsions, having the s ame bitumen concentration and an equivalent mean drop diameter, but with a unimodal distribution. It was also found that concentrated bimodal emulsion s behave like Newtonian fluids, while the unimodal counterparts are non-New tonian and show some pseudoplasticity. Because of their very simple rheolog ical behavior, bitumen in water bimodal emulsions are of great importance i n the processes of transporting, handling, and commercializing extremely vi scous hydrocarbons.