A. Milani et al., Two-dimensional mapping of residual stress-induced birefringence in differently-grown semiconductors for optical communication applications, MAT SCI E A, 288(2), 2000, pp. 205-208
Semiconductor-based bulk optical modulators and switches demand material ho
mogeneity and lack of residual birefringence, to guarantee low attenuation
and noise performances. The fulfillment of such requirements strongly depen
ds on crystal growth technique and machinery process. We have developed a p
olarimetric two-dimensional mapping technique at lambda=1.5 mu m, that comp
aratively characterizes the residual stress-induced birefringence of semico
nductor modulator rods from a functional point of view, by evaluating the d
istribution of effective birefringence and estimating the overall noise fig
ure of merit (cross-talk) for optical switching applications. We have exami
ned high-resistivity CdTe rods grown by the horizontal Bridgman technique,
and compared results to data from GaAs single crystals grown by horizontal
Bridgman, liquid encapsulated Czochralski and vapor pressure controlled Czo
chralski. The birefringence has been measured with a resolution in the Delt
a n approximate to 10(-7) range, spatial resolution can be adjusted, reachi
ng 10 mu m. The performance of CdTe samples is strongly affected by the pre
sence of dislocations and related localized stress fields, and acceptable p
erformance is reached only for large diameter optical beams, which average
birefringent effects on the cross-sectional area of the rod. High volume de
nsity of dislocations is intrinsic to single crystals grown by the Bridgman
method. Growing techniques from the vapor phase usually result in more hom
ogeneous samples. Therefore, we think that the development of a suitable va
por phase growth method is the key to obtain semi-insulating CdTe bulk crys
tals to be used for high-performance optical modulation and switching. (C)
2000 Elsevier Science S.A. All rights reserved.