Initial stages of the ion beam mixing process in Ag/Pd multilayers are anal
yzed using X-ray diffraction. The interface spread caused by ion irradiatio
n is reflected in changes in the relative intensities of satellite superlat
tice peaks. Diffraction profiles measured after ion irradiation are interpr
eted using computer programs based on a Monte Carlo simulation. The thickne
ss of mixed interface regions and interplanar distances of both components
of multilayer are determined for each stage of ion irradiation. The determi
ned mixing parameter is independent of the multilayer period and of the rel
ative concentrations of components. A stress relaxation effect is observed
for low ion doses. (C) 2000 Published by Elsevier Science S.A.