A new high density plasma SiO2 etching process based on CHF3/CH4 mixture is
investigated by means of plasma diagnostics and surface analysis. Selectiv
ity as high as 15 with respect to silicon has been obtained. Besides, a sli
ght decrease of the SiO2 etch rate is observed as compared to CHF3. Deposit
ion of a carbon-rich fluorocarbon layer on the SiO2 is thought to play an i
mportant role in the etching mechanism, as generally described for Si.