Justification of relativistic Dirac-Hartree-Fock and configuration interaction

Citation
Cf. Bunge et al., Justification of relativistic Dirac-Hartree-Fock and configuration interaction, MOLEC PHYS, 98(16), 2000, pp. 1067-1073
Citations number
53
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR PHYSICS
ISSN journal
00268976 → ACNP
Volume
98
Issue
16
Year of publication
2000
Pages
1067 - 1073
Database
ISI
SICI code
0026-8976(200008)98:16<1067:JORDAC>2.0.ZU;2-5
Abstract
Before knowing that the relativistic Hamiltonian H does allow the existence of bounded states (H is unbounded from below and from above), the existenc e of SCF and beyond SCF solutions had to be assumed as an act of faith vind icated by consistent numerical results. A recent theorem showing the existe nce of such bounded states furnishes a rigorous framework for the relativis tic theory of electronic bounded states.