BARBIER-TYPE ALLYLATION OF ALDEHYDES WITH ACTIVE METALLIC ANTIMONY

Authors
REN PD JIN QH YAO ZP
Citation
Pd. Ren et al., BARBIER-TYPE ALLYLATION OF ALDEHYDES WITH ACTIVE METALLIC ANTIMONY, Synthetic communications, 27(16), 1997, pp. 2761-2767
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
27
Issue
16
Year of publication
1997
Pages
2761 - 2767
Database
ISI
SICI code
0039-7911(1997)27:16<2761:BAOAWA>2.0.ZU;2-G
Abstract
Highly reactive antimony, prepared by the NaBH4 reduction of SbCl3, in duced allylation of aldehydes with allylic bromide in DMF/H2O solvent to give good yields of the corresponding homoallylic alcohols with hig h regio- and chemo- selectivity.