The additional information provided by field emission resonance spectra sig
nificantly increases the potential of the mechanically controllable break j
unction technique. We have found that the pronounced three-dimensional natu
re of the electrodes results in an extremely high sensitivity of the field
emission resonance spectra to the fine details of the surface geometry, ele
ctronic structure and electric field distribution at small electrode separa
tions. At larger distances a quasiclassical approximation can be used for t
he determination of the metal work function, precise calibration of the ele
ctrode relative displacement and discrimination between "blunt" and "sharp"
electrodes on the basis of the distance-voltage z(V) dependence. (C) 2000
Elsevier Science B.V. All rights reserved.