The optical properties of GaSb/Al0.4Ga0.6Sb multiple quantum well structure
s grown by molecular beam epitaxy on GaAs substrates were studied through a
bsorption and photoluminescence measurements. Despite the various difficult
ies in growing good quality GaSb-based heterostructures a clearly resolved
splitting between the absorption peaks related to the n = 1 heavy and light
hole excitons was observed in the energy range 0.85-1.15 eV even at room t
emperature. A detailed line shape analysis of the excitonic absorption peak
s has been carried out in the GaSb/(AlGa)Sb MQW system: the reliability of
such analysis was confirmed by the fact that the experimentally determined
ratio between heavy to light "in-plane" reduced masses is in excellent agre
ement with the ratio in the literature. The energies of the interband elect
ronic transitions, calculated within the envelope function approximation in
cluding strain effects, show a discrepancy with experiments interpreted in
terms of interfacial roughness. The values of band offset and nonparabolici
ty coefficients resulting from the analysis are in good agreement with the
data reported in the literature.