Discrimination of lattice oxygen species involved in the oxidative coupling of methane on a Mn mixed-Mg oxide

Authors
Kanno, T Horiuchi, J Kobayashi, M
Citation
T. Kanno et al., Discrimination of lattice oxygen species involved in the oxidative coupling of methane on a Mn mixed-Mg oxide, REACT KIN C, 70(1), 2000, pp. 73-80
Citations number
6
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
70
Issue
1
Year of publication
2000
Pages
73 - 80
Database
ISI
SICI code
0133-1736(200005)70:1<73:DOLOSI>2.0.ZU;2-Z
Abstract
Two functional lattice oxygens on the surface of a Mn-mixed Mg oxide were d istinguished in the oxidative coupling of methane: the oxygen of MgO, which was active for methyl radical formation, and that of a Mn-Mg oxide solid s olution, which was active for the dehydrogenation of ethane.