Synthesis of substituted 1H-4,5-dihydroimtdazolium salts by dehydrogenation of imidazolidines

Citation
A. Salerno et al., Synthesis of substituted 1H-4,5-dihydroimtdazolium salts by dehydrogenation of imidazolidines, SYN COMMUN, 30(18), 2000, pp. 3369-3382
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
30
Issue
18
Year of publication
2000
Pages
3369 - 3382
Database
ISI
SICI code
0039-7911(2000)30:18<3369:SOS1SB>2.0.ZU;2-S
Abstract
A study is presented on the scope of the method to obtain 1H-4,5-dihydroimi dazolium salts 3 by dehydrogenation of 1,3-di and 1,2,3-trisubstituted imid azolidines 2. Of the dehydrogenating agents used, N-bromoacetamide leads to the best results, providing a simple and general method to prepare salts 3 .