Reactivities of carbonyl-activated angular and vinyl chlorine substituentsin chloranyl-cyclopentadiene adduct toward nucleophiles. Synthesis of new 1,4-benzoquinones containing an unusual ortho pattern of substitution.

Authors
Di Vitta, C Wladislaw, B Marzorati, L
Citation
C. Di Vitta et al., Reactivities of carbonyl-activated angular and vinyl chlorine substituentsin chloranyl-cyclopentadiene adduct toward nucleophiles. Synthesis of new 1,4-benzoquinones containing an unusual ortho pattern of substitution., SYN COMMUN, 30(18), 2000, pp. 3413-3422
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
30
Issue
18
Year of publication
2000
Pages
3413 - 3422
Database
ISI
SICI code
0039-7911(2000)30:18<3413:ROCAAV>2.0.ZU;2-X
Abstract
Vinyl and angular chlorine atoms in chloranyl-cyclopentadiene adduct may be stepwise substituted by sulfur, nitrogen or oxygen nucleophiles to afford, after pyrolysis, highly substituted new quinones.