Simultaneous flow-injection measurement of hydroxide, chloride, hypochlorite and chlorate in Chlor-alkali cell effluents

A flow injection method is reported for the simultaneous determination of h ydroxide, chloride, hypochlorite, and chlorate ions that exist in Chlor-alk ali cell effluents in concentrations ranging from sub-millimolar to several molar. The hydroxide concentration is determined by the heat of neutraliza tion of the; injected sample into an acidic carrier stream and the chloride concentration is calculated from the measured conductance data. For the me asurement of hypochlorite and chlorate, colorimetric iodometry is used. Iod ide is oxidized to iodine by OCl- and ClO3- in acid solutions. While room t emperature is sufficient for the reaction between OCl- and I-, the reaction between ClO3- and I- requires an elevated temperature. The different react ion requirements are utilized to differentiate between NaOCl and NaClO3, re spectively. (C) 2000 Elsevier Science B.V. All rights reserved.