Identification of metol degradation products under Fenton's reagent treatment using liquid chromatography-mass spectrometry

Citation
L. Lunar et al., Identification of metol degradation products under Fenton's reagent treatment using liquid chromatography-mass spectrometry, WATER RES, 34(13), 2000, pp. 3400-3412
Citations number
37
Categorie Soggetti
Environment/Ecology
Journal title
WATER RESEARCH
ISSN journal
00431354 → ACNP
Volume
34
Issue
13
Year of publication
2000
Pages
3400 - 3412
Database
ISI
SICI code
0043-1354(200009)34:13<3400:IOMDPU>2.0.ZU;2-R
Abstract
Many aromatic compounds are oxidized but not completely mineralized by Fent on's reagent. Little attention has so far been given to the identification of residual organic matter and the evaluation of its toxicity. In this work , the oxidation of metol [N-methyl-p-aminophenol] by Fe2+/H2O2 in the dark as a model for aromatic amines and alcohols was examined. Analysis of oxidi zed solutions was performed by both LC-electron impact (EI)-MS and LC-elect rospray ionization (ESI)-MS, It was checked that the degradation of metol t akes place via direct oxidation by Fe3+ and OH. attack. Intermediates amena ble to oxidation by OH. are basically partially oxygenated aromatic species , dimerization products and polymers. End products not amenable to oxidatio n by this radical are ferrycarboxylate complexes, which are non-toxic to UC 581 bacterial cells. These complexes fan be completely destroyed by irradia tion with light. The photo-Fenton reaction is therefore an effective choice for the in situ treatment of industrial effluents containing aromatic amin es and hydroxylated species. (C) 2000 Elsevier Science Ltd. All rights rese rved.