trans-Chloro(2-nitrobenzenethiol-ato-S)bis(triphenylphosphine-P)-palladium(II) monoacetone solvate

Authors
Aupers, JH Ferguson, G Glidewell, C Low, JN Wardell, JL
Citation
Jh. Aupers et al., trans-Chloro(2-nitrobenzenethiol-ato-S)bis(triphenylphosphine-P)-palladium(II) monoacetone solvate, ACT CRYST C, 56, 2000, pp. 945-947
Citations number
19
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
8
Pages
945 - 947
Database
ISI
SICI code
0108-2701(200008)56:<945:T>2.0.ZU;2-P
Abstract
Molecules of the title compound, [PdCl(C6H4NO2S)(PPh3)(2)] .- C3H6O, exhibi t a slight distortion from exact planarity at the Pd atom towards tetrahedr al, with P-Pd-P and Cl-Pd-S angles of 174.98 (3) and 174.19 (3)degrees, res pectively. The Pd-Cl and Pd-S bonds are, respectively, long [2.3550 (11) An gstrom] and short [2.3020 (12) Angstrom] for their types; the S-C bond is a lso very short [1.744 (4) Angstrom]. The solvating acetone molecule is link ed to one of the phosphine ligands by means of a CD H ... O hydrogen bond.