(Benzoylacetonato)chloro(1,10-phenanthroline)copper(II)

Authors
Elerman, Y Kara, H Ozcan, S Kendi, E
Citation
Y. Elerman et al., (Benzoylacetonato)chloro(1,10-phenanthroline)copper(II), ACT CRYST C, 56, 2000, pp. 950-951
Citations number
27
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
8
Pages
950 - 951
Database
ISI
SICI code
0108-2701(200008)56:<950:(>2.0.ZU;2-I
Abstract
The crystal structure of the title compound, chloro(1,10-phenanthroline-N,N ')(1-phenyl-1,3-butanedionato-O,O')copper(II), [CuCl(C10H9O2)(C12H8N2)], ha s been determined. The Cu II ion displays a distorted square-pyramidal coor dination, being linked to the two O atoms of the benzoylacetonate ligand an d the two N atoms of the 1,10-phenanthroline ligand in the basal plane, and the Cl atom in the apical site. The Cu-N, Cu-O and Cu-Cl bond lengths are 2.043 (2)/ 2.025 (2), 1.914 (2)/1.941 (2) and 2.485 (1) Angstrom, respectiv ely.