Bis[(R)-1-phenylethyl isocyanido]-(5,10,15,20-tetrakis{2,6-bis[(S)-2,2-dimethyl-1,3-dioxolan-4-ylmethyloxy]-phenyl}porphyrin)ruthenium(II) at 110 K

Authors
Galardon, E Lukas, M Le Maux, P Toupet, L Roisnel, T Simonneaux, G
Citation
E. Galardon et al., Bis[(R)-1-phenylethyl isocyanido]-(5,10,15,20-tetrakis{2,6-bis[(S)-2,2-dimethyl-1,3-dioxolan-4-ylmethyloxy]-phenyl}porphyrin)ruthenium(II) at 110 K, ACT CRYST C, 56, 2000, pp. 955-956
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
8
Pages
955 - 956
Database
ISI
SICI code
0108-2701(200008)56:<955:BI>2.0.ZU;2-A
Abstract
The geometry about the Ru atom in the title compound, [Ru(C9H9N)(2)(C92H108 N4O24)], is approximately tetragonal and the porphyrin ring is nearly plana r, while the C-N-R angles [169.3 (3) and 163.9 (3)degrees] of the isocyanid e ligands in the complex are different from the value of 180 degrees expect ed in the free ligand.