(4S,5S)-(+)-4-Hydroxymethyl-2,5-di-phenyloxazoline

Authors
Gzella, A Rozwadowska, MD
Citation
A. Gzella et Md. Rozwadowska, (4S,5S)-(+)-4-Hydroxymethyl-2,5-di-phenyloxazoline, ACT CRYST C, 56, 2000, pp. 981-982
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
8
Pages
981 - 982
Database
ISI
SICI code
0108-2701(200008)56:<981:(>2.0.ZU;2-C
Abstract
The absolute configuration of the title compound, alternatively called (+)- (4,5-dihydro-2,5-diphenyloxazol-4-yl)methanol, C16H15NO2, has been confirme d as 4S,5S. The hydroxymethyl group and phenyl ring at the asymmetric C ato ms exhibit beta and alpha orientations, respectively. The exocyclic C-C bon ds at the asymmetric C atoms are mutually anticlinal (- ac). The hydroxyl g roup and the N atom of the oxazoline ring are involved in an intermolecular hydrogen bond leading to chains of molecules.