Tribenzyl(eta(5)-pentamethylcyclopentadienyl)hafnium(IV)

Authors
Swenson, DC Guo, ZY Crowther, DJ Baenziger, NC Jordan, RF
Citation
Dc. Swenson et al., Tribenzyl(eta(5)-pentamethylcyclopentadienyl)hafnium(IV), ACT CRYST C, 56, 2000, pp. E313-E314
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
8
Pages
E313 - E314
Database
ISI
SICI code
0108-2701(200008)56:<E313:T>2.0.ZU;2-J
Abstract
The title compound, [Hf(C7H7)(3) (C10H15)], adopts a monomeric three-legged piano-stool structure. One benzyl ligand is disordered between two sites ( 44:56%) related by a similar to 30 degrees rotation about an axis defined b y the Hf atom and the ipso-C atom of the benzyl ligand.