Chloro(eta(6)-p-cymene)(2-methyl-5-oxo-7-phenyl-5,6-dihydro-2H-1,2,4-triazepine-3-thiolato-kappa N-2(4),S)ruthenium(II)

Authors
Aitali, M Itto, MYA Hasnaoui, A Riahi, A Karim, A Garcia-Granda, S Gutierrez-Rodriguez, A
Citation
M. Aitali et al., Chloro(eta(6)-p-cymene)(2-methyl-5-oxo-7-phenyl-5,6-dihydro-2H-1,2,4-triazepine-3-thiolato-kappa N-2(4),S)ruthenium(II), ACT CRYST C, 56, 2000, pp. E315-E316
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
8
Pages
E315 - E316
Database
ISI
SICI code
0108-2701(200008)56:<E315:C>2.0.ZU;2-R
Abstract
The novel title ruthenium(II) complex, [RuCl(C10H14)(C10H10N3OS)], was synt hesized from the reaction of 1,2,4-triazepine, a new class of bidentate lig ands, with [Ru(p-cymene)Cl-2](2). The 1,2,4-triazepine ligand is coordinate d to the metal centre through the N-4 and S atoms, forming a four-membered chelate ring. This is the first structural example of a transition metal co mplex containing a 1,2,4-triazepine ligand.