{2,2 '-[(R,R)-Cyclohexane-1,2-diylbis(nitrilomethylidyne)]bis[6-tert-butyl-4-(triphenylphosphoniomethyl)phenolato]-O,N,N ' O '}copper(II) dichloride hexakis(deuterochloroform) solvate

Authors
Pajunen, A Mutikainen, I Haikarainen, A Sipila, J Pietikainen, P
Citation
A. Pajunen et al., {2,2 '-[(R,R)-Cyclohexane-1,2-diylbis(nitrilomethylidyne)]bis[6-tert-butyl-4-(triphenylphosphoniomethyl)phenolato]-O,N,N ' O '}copper(II) dichloride hexakis(deuterochloroform) solvate, ACT CRYST C, 56, 2000, pp. E321-E322
Citations number
7
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
8
Pages
E321 - E322
Database
ISI
SICI code
0108-2701(200008)56:<E321:{'>2.0.ZU;2-Y
Abstract
The title compound, [Cu(C66H68N2O2P2)]Cl-2. 6CDCl(3), consists of complex c ations, chloride ions and deuterochloroform solvate molecules. The complex cation crystallizes in two different conformations. In both cases, Cu II io ns lie on twofold axes and the geometry around them is slightly distorted s quare planar. The dihedral angles between the N/Cu/N and O/Cu/O planes are 5.6 (9) and 3.9 (10)degrees for molecules A and B, respectively.