Aquabis(benzonitrile)(o-benzoquin-one diimine)(triphenylphosphine)ruthenium(II) bis(tetrafluoroborate) hydrate

Authors
Venegas-Yazigi, D Lever, ABP Lough, AJ Vega, A Paredes-Garcia, V Costamagna, J Latorre, R Latorre, N
Citation
D. Venegas-yazigi et al., Aquabis(benzonitrile)(o-benzoquin-one diimine)(triphenylphosphine)ruthenium(II) bis(tetrafluoroborate) hydrate, ACT CRYST C, 56, 2000, pp. E323-E324
Citations number
7
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
8
Pages
E323 - E324
Database
ISI
SICI code
0108-2701(200008)56:<E323:AD>2.0.ZU;2-K
Abstract
The Ru atom in the title compound, [Ru(C6H5CN)(2) {P-(C-6 H-5)(3)}{C6H4(NH) (2)}(H2O)](BF4)(2). H2O, has six-coordinate octahedral geometry, with a tra ns arrangement of the triphenylphosphine ligand and the water molecule. The asymmetric unit contains one complex cation, two tetrafluoroborate anions and one solvent water molecule, which is disordered over two sites (ratio o f occupancies 0.70:0.30).