A single crystal of La2CoO4.15 has been grown by the floating zone met
hod and characterised extensively by bulk magnetisation and neutron di
ffraction studies. Long range antiferromagnetic order (AFM) is observe
d below (227.7 +/- 0.5) K and at (103 +/- 2) K a new AFM phase appears
. The low temperature phase transition is associated with a first-orde
r structural phase transition from a high-temperature orthorhombic pha
se to a low-temperature tetragonal phase.