DC and AC conductivity of barium hydrogen phosphate (BaHPO4)

Citation
Tr. Trivedi et al., DC and AC conductivity of barium hydrogen phosphate (BaHPO4), CRYST RES T, 35(5), 2000, pp. 615-624
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CRYSTAL RESEARCH AND TECHNOLOGY
ISSN journal
02321300 → ACNP
Volume
35
Issue
5
Year of publication
2000
Pages
615 - 624
Database
ISI
SICI code
0232-1300(2000)35:5<615:DAACOB>2.0.ZU;2-B
Abstract
D.C. conductivity of the ferroelectric BaHFO4 is measured acid is found to lie between usual conductivities of semiconductor and insulator. its temper ature dependence shows intrinsic conduction in defective crystals due to H ions. The a.c. conductivity calculated from the measured dielectric consta nt follows sigma similar to omega(154), a power law. Frequency of 20 kHz re solves the resistivity peak of a.c. conduction into two Gaussians. The ln s igma vs f plots at different temperatures show an exponential dependence an d existence of a focal point.