We describe in this paper a process of filtration of highly viscous liquids
assisted by pressurized CO2, and we present preliminary results obtained d
uring the treatment of motor oils (two mineral oils and one used motor oil)
. Filtration and concentration runs are commentated in terms of permeate fl
ux enhancement and metal retention. The behavior of these fluids during fil
tration exhibits significant discrepancies from the one observed with previ
ously investigated model compounds. The permeate flux improvement is about
400% for mineral oils and about 200% for the used motor oil (P-CO2 = 15 Mfa
, Delta P = 1 MPa, T = 353 K, cutoff of the membrane: 356 kDa). The presenc
e of many pollutants can explain the lower improvement in the latter case.
The performance of the membrane with regard to the retention of metals is v
ery satisfactory: in the case of zinc and copper, the separation is higher
than 99.5%, The 32 h concentration run carried out: at 393 K made it possib
le to regenerate 96% in mass of the used oil and to confine the majority of
the metals in a black gum extremely viscous.