Ethylene oxide and propylene sulfide complexes of silver(I): Synthesis andcharacterization of [HB(3,5-(CF3)(2)Pz)(3)]Ag(OC2H4) and [HB(3,5-(CF3)(2)Pz)(3)]Ag(SC3H6)

Authors
Dias, HVR Wang, ZY
Citation
Hvr. Dias et Zy. Wang, Ethylene oxide and propylene sulfide complexes of silver(I): Synthesis andcharacterization of [HB(3,5-(CF3)(2)Pz)(3)]Ag(OC2H4) and [HB(3,5-(CF3)(2)Pz)(3)]Ag(SC3H6), INORG CHEM, 39(16), 2000, pp. 3724
Citations number
44
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
16
Year of publication
2000
Database
ISI
SICI code
0020-1669(20000807)39:16<3724:EOAPSC>2.0.ZU;2-D
Abstract
The synthesis and solid-state structures of [HB(3,5-(CF3)(2)PZ)(3)]Ag(OC2H4 ) and [HB(3,5-(CF3)(2)Pz)(3)]Ag-(SC3H6) are presented. The propylene sulfid e ligand shows a relatively large tilt toward the [HB(3,5-(CF3)(2)-Pz)(3)]A g moiety compared to the ethylene oxide ligand. [HB(3,5-(CF3)(2)Pz)(3)]Ag(O C2H4) and [HB(3,5-(CF3)(2)Pz)(3)]Ag(SC3H6) are rare examples of compounds f eaturing metal-epoxide and metal-thiirane bonding. [GRAPHICS]