Synthesis and structure determination of a novel diastereomeric diaminodichlorodisilane

Authors
Bohme, U Gunther, B Rittmeister, B
Citation
U. Bohme et al., Synthesis and structure determination of a novel diastereomeric diaminodichlorodisilane, INORG CH C, 3(8), 2000, pp. 428-432
Citations number
28
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
8
Year of publication
2000
Pages
428 - 432
Database
ISI
SICI code
1387-7003(200008)3:8<428:SASDOA>2.0.ZU;2-E
Abstract
Different aromatic diorganoamines were tested for their reactivity with 1,1 ,2,2-tetrachlorodimethyldisilane (1). Indole reacts easily with 1, tetrakis (indolyl)-1,2-dimethyldisilane (2) was isolated. The reaction of N-methylan iline with 1 yields (MePhN)(2)MeSi-SiMe( N MePh)Cl (3) and Cl(MePhN)MeSi-Si Me( N MePh)Cl (4) depending on the proportions of the starting materials. T he crystal structure of 4 shows that the compound crystallizes as separated pure enantiomeric crystals. The value of optical rotation was estimated. ( C) 2000 Elsevier Science S.A. All rights reserved.