M. Masili et al., Nonadiabatic calculations of the oscillator strengths for the helium atom in the hyperspherical adiabatic approach, J PHYS B, 33(14), 2000, pp. 2641-2652
Citations number
33
Categorie Soggetti
Physics
Journal title
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS
Energies and wavefunctions are calculated for the bound states of the heliu
m atom in the hyperspherical adiabatic approach by the full inclusion of no
nadiabatic couplings. We show that the use of appropriate asymptotic radial
boundary conditions not only allows the efficient calculation of energies
accurate up to a few ppm for the ground state but also gives increasingly p
recise results for high-lying excited states with a unique set of equations
. The accuracy of the wavefunctions is demonstrated by the calculation of o
scillator strengths in the length form for transitions between stares ii S-
1(e) and (n + 1) P-1(0) up to n = 29, in agreement with variational calcula
tions.