The problem of detection of few-electron states has been studied for spheri
cal quantum dots both with and without a donor centre. The confinement pote
ntial is assumed to be a three-dimensional spherical potential well of fini
te depth and range. The variational method has been applied to calculate bo
und states of one-, two-, and three-electron systems confined in donor-dope
d and undoped quantum dots. We have shown that the chemical potentials of t
he systems considered are significantly different, in contrast to the intra
band optical dipole transition energies, which are almost indistinguishable
. Therefore, the transport and capacitance spectroscopy techniques should y
ield clear evidence for the presence of a donor impurity in the quantum dot
.