Pm. Goldbart, Random solids and random solidification: what can be learned by exploring systems obeying permanent random constraints?, J PHYS-COND, 12(29), 2000, pp. 6585-6599
In many interesting physical settings, such as the vulcanization of rubber,
the introduction of permanent random constraints between the constituents
of a homogeneous fluid can cause a phase transition to a random solid state
. In this random solid state, particles are permanently but randomly locali
zed in space, and a rigidity to shear deformations emerges. Owing to the pe
rmanence of the random constraints, this phase transition is an equilibrium
transition, which confers on it a simplicity (at least relative to the con
ventional glass transition) in the sense that it is amenable to treatment b
y established techniques of equilibrium statistical mechanics. In this pape
r I shall review recent developments in the theory of random solidification
for systems obeying permanent random constraints, with the aim of bringing
to the fore the similarities of and differences between such systems and t
hose exhibiting the conventional glass transition. I shall also report new
results, obtained in collaboration with Weiqun Peng, on equilibrium correla
tions and susceptibilities that signal the approach of the random solidific
ation transition, discussing the physical interpretation and values of thes
e quantities both at the Gaussian level of approximation and, via a renorma
lization-group approach, beyond.