Addition of H-2 to a cationic iridium(I) complex: a study using parahydrogen NMR

Authors
Duckett, SB Field, LD Messerle, BA Shaw, WJ Soler, LP
Citation
Sb. Duckett et al., Addition of H-2 to a cationic iridium(I) complex: a study using parahydrogen NMR, J CHEM S DA, (14), 2000, pp. 2251-2253
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
1470479X → ACNP
Issue
14
Year of publication
2000
Pages
2251 - 2253
Database
ISI
SICI code
1470-479X(2000):14<2251:AOHTAC>2.0.ZU;2-Q
Abstract
Parahydrogen enhanced NMR signals are used to monitor the reaction between the cationic iridium(I) complex [Ir(BPM)(CO)(2)][BPh4] (BPM = bis(pyrazol-1 -yl)methane) and dihydrogen: four major products are formed in a cascade of reactions.