Dl. Clark et al., First single-crystal X-ray diffraction study of a lanthanide tricarbonate complex: [Co(NH3)(6)][Sm(CO3)(3)(H2O)]center dot 4H(2)O, J CHEM S DA, (13), 2000, pp. 1975-1977
Citations number
40
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
The first single-crystal X-ray diffraction study of a lanthanide tricarbona
te complex, namely [Co(NH3)(6)][Sm(CO3)(3)(H2O)]. 4H(2)O, is reported and r
eveals a zigzag chain structure of 9-coordinate samarium metal centers brid
ged by mu-eta(2):eta(1) carbonate ligands.