First single-crystal X-ray diffraction study of a lanthanide tricarbonate complex: [Co(NH3)(6)][Sm(CO3)(3)(H2O)]center dot 4H(2)O

Authors
Clark, DL Donohoe, RJ Gordon, JC Gordon, PL Keogh, DW Scott, BL Tait, CD Watkin, JG
Citation
Dl. Clark et al., First single-crystal X-ray diffraction study of a lanthanide tricarbonate complex: [Co(NH3)(6)][Sm(CO3)(3)(H2O)]center dot 4H(2)O, J CHEM S DA, (13), 2000, pp. 1975-1977
Citations number
40
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
1470479X → ACNP
Issue
13
Year of publication
2000
Pages
1975 - 1977
Database
ISI
SICI code
1470-479X(2000):13<1975:FSXDSO>2.0.ZU;2-D
Abstract
The first single-crystal X-ray diffraction study of a lanthanide tricarbona te complex, namely [Co(NH3)(6)][Sm(CO3)(3)(H2O)]. 4H(2)O, is reported and r eveals a zigzag chain structure of 9-coordinate samarium metal centers brid ged by mu-eta(2):eta(1) carbonate ligands.