Synthesis and molecular structures of a pair of tris(imidazolyl)phosphine cobalt-perchlorate complexes, {[Pim(Pri2)]Co(OClO3)}[ClO4] and {[Pim(Pri2)]Co(OH2)(HOMe)(OClO3)}[ClO4]

Authors
Kimblin, C Bridgewater, BM Churchill, DG Parkin, G
Citation
C. Kimblin et al., Synthesis and molecular structures of a pair of tris(imidazolyl)phosphine cobalt-perchlorate complexes, {[Pim(Pri2)]Co(OClO3)}[ClO4] and {[Pim(Pri2)]Co(OH2)(HOMe)(OClO3)}[ClO4], J CHEM S DA, (13), 2000, pp. 2191-2194
Citations number
27
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
1470479X → ACNP
Issue
13
Year of publication
2000
Pages
2191 - 2194
Database
ISI
SICI code
1470-479X(2000):13<2191:SAMSOA>2.0.ZU;2-W
Abstract
The cobalt-perchlorate complexes, {[Pim(2)(Pri)]Co(OClO3)}(ClO4) and {[Pim( 2)(Pri)]Co(OH2)(HOMe)(OClO3)}(ClO4), have been synthesized via the reaction of tris[2-(1,4-diisopropylimidazolyl)]phosphine [Pim(2)(Pri)] with Co(ClO4 )(2). 6H(2)O; the isolation of these species, as opposed to a hydroxide der ivative {[Pim(2)(Pri)]CoOH}(+), demonstrates the important role that steric interactions play in generating synthetic analogues for metal-substituted carbonic anhydrases.