Addition of the [((BuP)-Bu-t)(3)As](-) anion to the cyclopentadienyl ring of [(C5H5)M(CO)(3)Cl] (M = Mo, W)

Authors
Bashall, A Hopkins, AD Mays, MJ McPartlin, M Wood, JA Woods, AD Wright, DS
Citation
A. Bashall et al., Addition of the [((BuP)-Bu-t)(3)As](-) anion to the cyclopentadienyl ring of [(C5H5)M(CO)(3)Cl] (M = Mo, W), J CHEM S DA, (12), 2000, pp. 1825-1826
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
1470479X → ACNP
Issue
12
Year of publication
2000
Pages
1825 - 1826
Database
ISI
SICI code
1470-479X(2000):12<1825:AOT[AT>2.0.ZU;2-L
Abstract
Reactions of the [((BuP)-Bu-t)(3)As](-) anion with [(C5H5)M(CO)(3)Cl] (M = Mo, W) gives [(C5H4{As((PBu)-Bu-t)(3)})M(CO)(3)Cl] (M = Mo 1; M = W 2) as a result of addition to the C5H5 ring (with formal elimination of LiH), rath er than the expected product resulting from substitution of the metal-bonde d Cl ligand.