Synthesis and characterization of dialkylaluminium, gallium and indium [2-(N,N-dimethylaminomethyl)-4-methyl] phenoxides crystal structure of dimethylgallium [2-(N,N-dimethylaminomethyl)-4-methyl]phenoxide

Authors
Shen, YZ Pan, Y Gu, HW Wu, T Huang, XY Hu, HW
Citation
Yz. Shen et al., Synthesis and characterization of dialkylaluminium, gallium and indium [2-(N,N-dimethylaminomethyl)-4-methyl] phenoxides crystal structure of dimethylgallium [2-(N,N-dimethylaminomethyl)-4-methyl]phenoxide, MAIN GR MET, 23(8), 2000, pp. 423-427
Citations number
22
Categorie Soggetti
Chemistry
Journal title
MAIN GROUP METAL CHEMISTRY
ISSN journal
07921241 → ACNP
Volume
23
Issue
8
Year of publication
2000
Pages
423 - 427
Database
ISI
SICI code
0792-1241(2000)23:8<423:SACODG>2.0.ZU;2-D
Abstract
Reactions of Group 13 metallic alkyls R3M (R = Me, M = Al, Ga, In; R = Et, M = Al, Ga) with 2-(N,N-dimethylaminomethyl)-4-methylphenol give five intra molecularly coordinated organometallic complexes in high yields. The compou nds obtained have been characterized by elemental analysis, H-1 NMR and mas s spectroscopy. Single-crystal X-ray analysis has established the molecular structure of dimethylgallium[2-(N,N-dimethylaminomethyl)-4-methyl]phenoxid e, in which the Ga atom is four coordinate in the structure.