Crystal and molecular structures of dichloromethyl[1-methyl-2(3H)-imidazolinethione]phenyltin(IV)

Authors
Casas, JS Garcia-Martinez, E Garcia-Tasende, MS Sanchez, A Sordo, J Vazquez-Lopez, EM Vidarte, MJ
Citation
Js. Casas et al., Crystal and molecular structures of dichloromethyl[1-methyl-2(3H)-imidazolinethione]phenyltin(IV), MAIN GR MET, 23(8), 2000, pp. 437-442
Citations number
26
Categorie Soggetti
Chemistry
Journal title
MAIN GROUP METAL CHEMISTRY
ISSN journal
07921241 → ACNP
Volume
23
Issue
8
Year of publication
2000
Pages
437 - 442
Database
ISI
SICI code
0792-1241(2000)23:8<437:CAMSOD>2.0.ZU;2-Z
Abstract
The complex [SnMePhCl2(Hmimt)] (Hmimt = 1-methyl-2(3H)-imidazolinethione) h as been synthesized by reaction of SnMePhCl2 and Hmimt in chloroform and ch aracterized by elemental analysis, mass spectrometry, NMR (H-1,C-13 and Sn- 119), IR and Raman spectroscopy, and X-ray diffractometry. The tin atom is in a trigonal bipyramidal environment, coordinated to two C atoms [Sn-C(6)= 2.125(4), Sn-C(12) = 2.109(4) Angstrom], two Cl atoms [Sn-Cl(1)= 2.5069(11 ), Sn-Cl(2)= 2.6107(12) Angstrom] and an S [Sn-S = 2.4760(11) Angstrom]. In termolecular N(H)... Cl hydrogen bonds give rise to weakly bonded dimers.