The results from an X-ray spectral analysis of a large sample of quasars, o
bserved with ASCA, are presented. The sample was selected to include all AS
CA observations of quasars, with z > 0.05 and M-v < -23.0, available up to
1998 January. The data reduction leaves 62 quasars, 35 of which are radio-l
oud and 27 radio-quiet, suitable for spectral analysis. Differences are fou
nd between the radio-quiet quasars (RQQs) and the radio-loud quasars (RLQs)
: the RLQs have flatter X-ray spectra (Gamma similar to 1.6), with little i
ron line emission or reflection, and are more X-ray luminous than the softe
r (Gamma similar to 1.9) RQQs, ill agreement with previous studies. A corre
lation between Gamma and optical H beta was also found for the radio-quiet
quasars in this sample, whereby the steepest X-ray spectra tend to be found
in those objects with small H beta widths. The correlation is significant
at >99 per cent confidence, confirming the well-known trend between Gamma a
nd H beta FWHM in Seyfert Is, but at higher luminosities. Other spectral co
mplexities are observed from this sample. A soft X-ray excess, with blackbo
dy temperatures in the range 100-300 eV, is seen in many low-z radio-quiet
quasars. In most cases the temperatures are probably too hot to originate d
irectly from the disc and could imply that some reprocessing is involved. I
ron K-line emission features are also found in the RQQs, but often from par
tially ionized material, indeed, in the highest-luminosity RQQs there is ne
ither evidence for iron line emission nor the reflection component expected
from disc reflection models. These observations can be explained by an inc
rease in the quasar accretion rate with luminosity. leading to an increase
in the ionization state of the surface layers of the disc. The occurrence o
f ionized or 'warm' absorbers is rare in this sample, with only five detect
ions in low-z objects. However, excess neutral X-ray absorption is found to
wards several of the high-z predominantly radio-loud, quasars. Although fou
nd to increase with quasar redshift, this 'intrinsic' absorption may be ass
ociated with radio-loud active galactic nuclei.