The study of the reaction between thiophosphoryl esters and boron tribromide. The synthesis of oxathiaphosphaboretanes

Authors
Lewkowski, J Mortier, J Vaultier, M
Citation
J. Lewkowski et al., The study of the reaction between thiophosphoryl esters and boron tribromide. The synthesis of oxathiaphosphaboretanes, PHOSPHOR SU, 162, 2000, pp. 1-14
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
162
Year of publication
2000
Pages
1 - 14
Database
ISI
SICI code
1042-6507(2000)162:<1:TSOTRB>2.0.ZU;2-G
Abstract
Reactions between three thiophosphoryl esters and boron tribromide are repo rted. O,O,O-triethyl phosphorothionate (1) and O,O-diethyl methanephosphono thionate (5) gave substituted oxathiaphosphaboretanes 4 and 7 respectively. O-methyl diphenyl-phosphinothionate (9) led to the complex 11 and the corr esponding oxarhiaphosphaboretane 12. In order to establish the mechanism, r eactions were monitored by the multinuclear NMR spectroscopy.