Zinc chlorochromate nonahydrate [Zn(ClCrO3)(2).9H(2)O] is a useful reagentfor the solvent-free and in solution oxidative deprotection of trimethyl- and tert-butyldimethylsilyl ethers

Authors
Firouzabadi, H Gholizadeh, M Fakourpour, M
Citation
H. Firouzabadi et al., Zinc chlorochromate nonahydrate [Zn(ClCrO3)(2).9H(2)O] is a useful reagentfor the solvent-free and in solution oxidative deprotection of trimethyl- and tert-butyldimethylsilyl ethers, PHOSPHOR SU, 155, 1999, pp. 81-87
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
155
Year of publication
1999
Pages
81 - 87
Database
ISI
SICI code
1042-6507(1999)155:<81:ZCN[IA>2.0.ZU;2-T
Abstract
Primary and secondary tert-butyldimethylsilyl and trimethylsilyl ethers are oxidized to their corresponding carbonyl compounds with zinc chlorochromat e nonahydtate (ZCCNH) in dichloromethane or under solvent free conditions i n good yields, For comparison, we have also studied the reactions with pyri dinium chlorochromate (PCC) under similar reaction conditions.