We present a review of novel investigation results related with the thermol
uminescent and dosimetric properties of detectors based on potassium halide
s doped with divalent europium, such as KCl : Eu2+, KBr : Eu2+ and the crys
talline series KCl1-xBrx : Eu2+. We investigated both the existent defects
in the crystals and those that are generated by radiation and their interac
tion, trapping and room-temperature recombination mechanisms in thermally s
timulated light emission. The spectral response during the recombination st
age was obtained through simultaneous measurements of temperature, emitted
light intensity and emission wavelength by using an automated thermolumines
cence system,with optical fiber couplings and a diode array as detection de
vice. In this manner, it was possible to identify the involved defects in t
he thermoluminescent processes. Finally, since all potassium halide crystal
s contain the isotope K-40 (0.0117%) with a half-life of 1.28 x 10(9) years
, a self-irradiation effect is produced with an equivalent irradiation dose
of 4.9 mu Gy/h. Taking advantage of this self-irradiation effect, we devel
op a new and simple calibration method for thermoluminescent dosimeters, wh
ich has a marginal error of approximate to 2%. The shift in the measurement
s produced by this error is comparable with the obtained error from other s
ophisticated and expensive calibration methods. Even more, the self-irradia
tion phenomenon renders the possibility to make corrections in environmenta
l radiation measurements, for including climatic effects and other external
factors.