NOVEL ENTRY INTO BENZO[C]PHENANTHRIDINE SYSTEMS THROUGH A TANDEM ALKENE ACYLATION-CYCLODEHYDRATION

Authors
SANMARTIN R DEMARIGORTA EM MORENO I DOMINGUEZ E
Citation
R. Sanmartin et al., NOVEL ENTRY INTO BENZO[C]PHENANTHRIDINE SYSTEMS THROUGH A TANDEM ALKENE ACYLATION-CYCLODEHYDRATION, Heterocycles, 45(4), 1997, pp. 757-763
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
45
Issue
4
Year of publication
1997
Pages
757 - 763
Database
ISI
SICI code
0385-5414(1997)45:4<757:NEIBST>2.0.ZU;2-1
Abstract
2-Alkylbenzo [c]phenanthridines have been obtained by an overall high yielding synthetic methodology. Key steps involve Peterson methylenati on and an efficient one-pot alkene acylation-cyclization. Smooth oxida tion to the benzo[c]phenanthridinone system is also reported.