ONE-POT SYNTHESIS OF SELENIDES CONTAINING POLYARYLTHIO-ETHER MOIETY

Authors
SHIN SS KIM K
Citation
Ss. Shin et K. Kim, ONE-POT SYNTHESIS OF SELENIDES CONTAINING POLYARYLTHIO-ETHER MOIETY, Heterocycles, 45(4), 1997, pp. 795-803
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
45
Issue
4
Year of publication
1997
Pages
795 - 803
Database
ISI
SICI code
0385-5414(1997)45:4<795:OSOSCP>2.0.ZU;2-U
Abstract
The reactions of 5-arylthianthreniumyl perchlorates with sodium hydrog en selenide in ethanol and lithium n-butylselenolate in tetrahydrofura n under nitrogen at reflux afforded bis[2-(2-arylthiophenylthio)phenyl ] selenides and 2-arylthio-2'-(n-butylseleno)diphenyl sulfides in 26 - 83% and 23 - 98% yields, respectively. A sulfurane mechanism is propo sed.