We address several estimation problems in quantum optics by means of the ma
ximum-likelihood principle. We consider Gaussian state estimation and the d
etermination of the coupling parameters of quadratic Hamiltonians. Moreover
, we analyze different schemes of phase-shift estimation. Finally, the abso
lute estimation of the quantum efficiency of both linear and avalanche phot
odetectors is studied. In all the considered applications, the Gaussian bou
nd on statistical errors is attained with a few thousand data.