Oxide film growth by molecular beam epitaxy for the purpose of preparing me
tal oxides for surface science studies is discussed and reviewed. Critical
issues such as the choice of oxidizing gas, the selection of substrates, cr
ystal symmetry and lattice match, interface chemistry, and the relationship
of these issues to the materials science of oxide-on-metal and oxide-on-ox
ide film growth are discussed. Recent work on the growth of select, represe
ntative oxides that span the ranges of crystal structure, metal oxidation s
tate, and stoichiometry is reviewed and used to illustrate the basic materi
als science. (C) 2000 Elsevier Science B.V. All rights reserved.